為何水能溶解大量的鹽類？
水是很好的溶劑極易溶解鹽類，即使陰陽離子經由靜電的交互作用，很強的鍵結在一起，在水中還是可以很容易的被解離。
這是因為，水分子可以和離子結合產生 “水合離子” (Hydrated ions)。離子的半徑很小，電荷大的離子會與水分子強力的交互作用，由水分子在離子的周圍緊密排列。這時候，陽離子會與帶負極矩的氧原子相互作用，而陰離子則形成相反的結構。
因此，與純水相較，離子溶液中，離子周圍的水分子間的結構，有很大的不同。當離子濃度變高，單位離子的水分子數便會減少，離子的水合 (Hydration)（圖１）反應便難發生。
當溶質 (Solute) 為疏水性物質時，由於周圍的水分子不會與溶質分子相結合，水分子間的結合因而更強。水能夠溶解各種物質，溶解度則因物質而異，這與水分子間具有空隙結構，以及是否形成水合離子有關。
總而言之，存在於自然界，我們日常所接觸的水，不只是 “H2O”，而是含有各種物質的水溶液。
圖１、 Frank-Wen 的水合 (hydration) 模式
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